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The 42-year-old goalkeeper has been sidelined since early May and has yet to join a Hearts squad this season as he works towards regaining full fitness following a neck injury.
With 81 caps to his name, Gordon takes the place of club teammate Zander Clark, and both Max Johnston from Derby County and Dominic Hyam from Blackburn Rovers are also out of the lineup.
Scotland has secured four points after starting with a goalless draw in Denmark and a 2-0 win against Belarus in Hungary.
The Greek team is set to visit Hampden Park on October 9, while Belarus will be in Glasgow three days later, with both games broadcast live on the BBC.
Greece, who won against Belarus but lost to Denmark in Athens, have fond memories of their last visit to Hampden.
After being behind 1-0 from the first leg of a Nations League play-off in March, the Greek side emerged victorious with a convincing 3-0 win, marking Gordon's latest international appearance.
With head coach Steve Clarke choosing a more compact squad, there is no place for Hearts captain Lawrence Shankland, who has scored seven goals this season, nor for Middlesbrough striker Tommy Conway.
Anthony Ralston, who had previously withdrawn from the last squad alongside fellow Celtic full-back Kieran Tierney, made his return to action for his club at the weekend after being out for a month.
Angus Gunn secured two clean sheets for Scotland earlier this month but has not played for Nottingham Forest since his summer signing, while Rangers' goalkeeper Liam Kelly has only appeared against Alloa Athletic in the Premier Sports Cup this season.
Scotland squad
Goalkeepers: Gordon (Heart of Midlothian), Gunn (Nottingham Forest), Kelly (Rangers)
Defenders: Hanley (Hibernian), Hendry (Al-Etiffaq), Hickey (Brentford), McKenna (Dinamo Zagreb), Ralston (Celtic), Robertson (Liverpool), Souttar (Rangers), Tierney (Celtic)
Midfielders: Christie (Bournemouth), Ferguson (Bologna), Gannon Doak (Bournemouth), Gilmour (Napoli), McGinn (Aston Villa), McLean (Norwich City), McTominay (Napoli), Miller (Udinese)
Forwards: Adams (Torino), Bowie (Hibernian), Dykes (Birmingham City), Hirst (Ipswich Town)
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